ZIRCOAT - The versatile refractory coat with a many faceted role


The making of Zircoat
Typical Properties
Main Characteristics & Advantages
Applications
Procedure for Application of Zircoat to Chimneys & Ducts
Mixing of Zircoat
Guidelines to use Zircoat efficiently
Zircoat®-HT & Zircoat®-M

Applications


Zircoat with its high concentration of Zirconia, resists harsh chemical attacks at high and low temperatures. Around 3mm thick Zircoat coating can work wonders at ambient to 1800° C temperature.

5mm thick Zircoat coating offers as good a protection and insulation as a 130mm thick insulation fire brick. Zircoat prevents leakage of hot gases from heating chambers, thus maximum heat energy is preserved, wear and tear on the Zircoated surface is minimised and coating lasts longer.

Zircoat has unlimited applications and is used in the following areas where continuous and high temperature heating is found hazardous, specially in the heating chambers constructed with conventional materials.

   

Ceramics / Glass

Aluminium, brass and other nonferrous metals

Chemicals and fertilizers

Pulp and paper

Natural and other gases

Petroleum and hydrocarbon

Iron and steel

Marine and shipping

Cement

Sugar

Coating of kiln furniture, graphite and carbon crucibles. Zircoat coating will be of great benefit to use in the above areas as well as in domestic boilers, induction furnaces, rotary kilns, chimneys, ducts, etc., where fuel oil, gas or electricity are used for heating purpose.

   

Nonferrous Metal Industry

Zircoat is excellent for use in ferrous and nonferrous metal and other alloy industries. In aluminium, brass and its alloy industries, alumina refractory bricks which come in contact with molten aluminium or other nonferrous metals get corroded faster because their alumina content gets leached out. Zircoat which contains higher percentage of Zirconia in its residual is incompatible with molten metals. Therefore 3 to 5mm thick Zircoat coating on the face of refractory brick linings acts as a barrier and an armour to molten metals which arrests leaching of bricks, thus considerably enhancing the life of the heating chambers

 

Iron & Steel Industry

 

In cast iron and steel industry, apply around 6mm thick Zircoat between ganister and steel shell of the heating chambers of the cupola and accordingly suitable thickness coating for patching receivers, ladles, funnels, spouts etc., and over refractory bricks in reheat furnaces, soaking pits, open hearth floors, furnace doors, sloping floors etc.

Zircoat is used as a lubricant in the preparation of steel ingots for better quality and better finish of steel plates, castings etc.


Zircoat acts as a barrier and as an armour coat on the linings of electric furnace, producing special grade steels.

 

Chemical Industry

 

In many chemical processes, corrosive waste gases and chemicals at high temperature cause havoc to the steel structures, such as chimneys, ducts, furnace shells etc. Waste gases usually contain oxides of sulphur and vanadium. Even at low temperature, the area of acid-resistant bricks collapses because the cement mortar decays under the attack of sulphuric acid. In such cases, Zircoat coating increases the life of heating systems considerably due to its resistance to acids and waste gases. The service life of chimneys, steel shells and ducts can be extended multi folds if coated with Zircoat.

Fertilizer Industry

 

Generally frequent breakdowns are experienced in high temperature lones. In chemical processing units 3 to 5mm thick Zircoat will work as a barrier coat between heat transfer walls and corrosive chemical gases. This prevents costly breakdowns.

 

Town and Natural Gas Industry

 

A process called cyclic process, carries out the conversion of waste chemicals from oil refineries to industrial heating gas or town gas. Waste refinery gases and heavy naphtha are heated up for a few minutes in converters, where temperature suddenly rises from 105 to 980°C.

This tremendous temperature bounce occurs every couple of minutes; the thermal shock, thus developed can shatter the refractory linings in no time, which can cause explosion of semiburnt gases under pressure-resulting in heavy losses.


12mm thick Zircoat coating on the steel sections of the reacting areas of gas producing units will considerably increase the service life of chambers. The coatings can perform satisfactorily and offer prolonged protection. The life of heat transfer units of domestic and industrial boilers can be improved further by applying 3 to 4mm thick Zircoat over the refractory lining.

 

Shipping Industry

 

In ships, furnaces/boilers producing heat for generation of steam are fired with fuel oil. Because of months of nonstop operation of these furnaces/boilers, refractories get severely damaged due to the hot corrosive gases developed from fuel oil. At elevated
temperature, presence of small percentage of sulphur-dioxide, trioxide, vanadium pentoxide etc. damages refractory brick work. 3 to 4mm thick Zircoat applied on the refractory brick lining and also if used as a brick lining mortar, will enhance the life of furnaces/boilers considerably. Zircoat is found as an excellent mortar for laying new refractory brick lining in high and low temperature furnaces and kilns.

 

Petroleum and Hydrocarbon Industry

 

A huge amount of heat is vital for smooth and efficient running of a refinery. 260 to 2000° C temperature is employed continuously to crack down the crude oil and convert it to useful end products. The refinery runs more economically if the heating process is kept uninterrupted. Continuous high temperature corrodes the plant faster. Zircoat is an ideal remedy to protect the plant from corrosion.

 

Pulp and Paper Industry

 

High consumption of thermal energy is necessary for chemical conversion of wood into paper pulp and subsequent recovery of unreacted chemicals involves reliable refractory structures. Regions of high mechanical abrasion (as in ash flumes, the hoods of lime kilns and boilers in which heavy fuel oils are burned) often sufferfrom rapid erosion.

Severe spalling of refractories can occur when they are subjected to violent and and wet fuel comes in contact with hot furnace walls.

In this and in many chemical industries, problem of normal refractory wear developed from thermal or mechanical stresses is further aggravated by chemical attacks by reactive substances present in or produced by pulping or recovery process. Zircoat refractory coating is exceptionally stable and durable under conditions of thermal, mechanical and chemical onslaught encountered in the pulping process. 3 to 4mm thick Zircoat coating can increase the service life of heating systems by many folds.

 

Sugar Industry

 

In the sugar industry, plant managers will find Zircoat as an ideal cost-saving remedy for speedy repairs and maintenance of combustion chambers in lime kilns, pulp dryers, steam boilers, gas fired and oil-fired furnaces or wherever sugarcane waste is burned as a fuel.

Zircoat has proved a reliable, economical and cost-saving remedy in sugar producing mills. As a rule, plant repairs are generally carried out before the peak season starts when sugarcane juice is in abundance.

Harvesting of sugarcane keeps the plant working at optimum capacity for four to five months at a time. For the rest of the year the plant remains idle when patching and repairs can be conveniently carried out. In producing sugar from sugarcane, a large amount of sugarcane waste is burned as a fuel. This process produces hazardous chemical gases, which are corrosive at elevated temperatures. These chemical gases damage most refractories and firebricks, causing heavy breakdowns, which lead to great financial losses. Zircoat is found to be the most suitable remedy for speedy repairs of damaged areas.

 

Use of Zircoat in Induction Melting Furnace

 

The refractory brick lining between electric bobbins and silica ramming is the vital part of the induction melting system, and sensitive to thermal shock and physical wear.

Zircoat is used to reinforce these refractory bricks by trowelling with 3 to 4mm thick coating on outside and 5 to 6mm thick coating on inside refractory brick walls. Coating has to be properly dried up to set it hard.

After proper setting of Zircoat, silica sand has to be rammed in between the steel sleeve and 5mm thick asbestos or mica sheet to form an average silica wall thickness of 200mm. Melting of steel starts and the steel sleeve is allowed to melt away and get dissolved in the molten steel. After removing the molten metal from the trough, coating of pure silica is formed on top of the Zircoat coating.

The brick wall is thus reinforced by Zircoat and it becomes super resistant to wear and sudden break downs due to thermal shocks. After repeated usage of Zircoat, service life of furnace can be increased multi folds.

 
[A] Terminals Bobbin
[B] 3 to 4mm Zircoat
[C] High Grade Refractory Bricks
[D] 5 to 6mm Zircoat
[E] 5 to 6mm Mica / Asbestos Sheet
[F] Rammed Pure Silica Sand 200mm

ZIRCOAT INCREASES OUTPUT MANY FOLDS

 

 

Induction Melting Furnaces

 

Induction furnaces are used for melting ferrous and nonferrous rnetals. During the metal melting process, generally following problems are observed:

   
Rammed silica lining cracks due to thermal shocks.
Slagging of molten metal passage obstructs free flow of metals.
Eroding of silica lining.
Faster leaching out of refractory bricks which came in contact with molten metal.
Cracking of bricks and escape of molten metals.
Molten metals getting contaminated because of leached out constituents from lining bricks.
Zircoat is excellent to protect the heating system from above problems.

 

Kiln Furniture

 

Life of silicon carbide, mullite, alumina and cordierite refractory kiln furniture can be increased considerably by brushing or spraying with 1 to 2mm thick Zircoat.

 

Carbon / Graphite Crucibles

 

Crucibles are used for melting of ferrous and non ferrous metals. In metal melting process these crucibles are severely affected by molten metals at elevated temperatures, and it is generally experienced that they fail in just few charges.

Life of these expensive crucibles can be extended considerably by applying 2 to 3mm thick Zircoat coating on the inside and outside walls of crucibles.

Since Zircoat is incompatible (unfriendly) with carbon / graphite, following procedure is suggested for coating the crucibles.

 

Form a brushable Zircoat paste by mixing 5% Sodium Silicate solution in clean tap water. Ensure that crucible walls to be coated are rough and clean enough so that the coating adheres well over them. Apply 2 to 3mm thick Zircoat by brushing and allow the coated areas to dry out for a couple of days in warm atmosphere. The first heating of crucibles should be slower than normal. Around 2mm thick Zircoat coating can double the life of crucibles.
Caution: Improper drying of Zircoat coated crucibles may cause cracking/shattering during first heating.

 

Rotary Kilns

 

Zircoat is also an ideal and excellent refractory coating for rotary kilns, chimneys, ducts etc. 25mm thick Zircoat coating is sufficient for obtaining superior results. It reduces the gross weight of the rotary kiln and eliminates the risk of thermal shock damages.

   
Procedure for application of Zircoat to Rotary Kilns
Weld 6mm dia x 57mm L steel studs to the inside tubular kiln chamber wall at (12") 305mm centres.

Apply around 25mm thick Zircoat coating (in convenient small thickness layers) on the bottom half of the cylinder and fasten a mild steel wire mesh to the bolts over the coated area and press it tightly. The Zircoat coated shell has to be heated for around 24 hours at temperature 200°C to completely dry out the moisture and set the Zircoat hard.

After thoroughly drying out the Zircoat, again apply a second coat of 25mm thick Zircoat on the surface of wire mesh and repeat a further layer of wire mesh tightly secured over the coated area, once again thoroughly dry up the coated area at 200°C for further period of around 24 hours. This makes total thickness of Zircoat coating around 55mm above the steel shell. Again tightly fix up the wire mesh over the coated area and apply a final coat of around 5 to 6mm to ensure that the steel studs are totally immersed in Zircoat. System should be heated up for around 54 to 60 hours at 200°C and ensure that all the moisture is completely removed. After that the temperature can be increased at the usual rate.

 
 
 
 

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